Structure and curing mechanism of resol phenol-formaldehyde prepolymer resins
نویسندگان
چکیده
منابع مشابه
Characterization of Phenol-Formaldehyde Prepolymer Resins by In Line FT-IR Spectroscopy
Different resol phenol-formaldehyde prepolymer resins have been synthesized with different formaldehyde / phenol ratios. The phenolic resin composition depends on monomer ratio, catalyst, reaction conditions, and residual free monomers. Temperature and pH conditions under which reactions of phenols with formaldehyde are carried out have a profound effect on the characteristics of the resulting ...
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In order to study the thermal stability of accelerated-curing PF resin, the curing behavior of fresh PF resin was investigated in the presence of single accelerator of methylolurea derivatives (MMU), magnesium hydrate (Mg(OH)2), 25% aqueous solution of sodium carbonate (Na2CO3), and propylene carbonate (PC). Also their optimum combination was added in fresh PF resin. The thermal stability of cu...
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Understanding wetting behavior and surface coverage of resins on a wood surface is important to obtain satisfactory adhesion and optimize adhesive application for wood composite manufacturing. Sessile and micro-droplets of ureaand phenol-formaldehyde (UF and PF) resins were generated on wood surfaces to observe wetting behaviors using three directional image generation system and atomic force m...
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Wood liquefaction was conducted at a 2/1 phenol/wood ratio in two different reactors: (1) an atmospheric three-necked flask reactor and (2) a sealed Parr reactor. The liquefied wood mixture (liquefied wood, unreacted phenol, and wood residue) was further condensed with formaldehyde under acidic conditions to synthesize two novolac-type liquefied wood/phenol/formaldehyde (LWPF) resins: LWPF1 (th...
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ژورنال
عنوان ژورنال: Proceedings of the Estonian Academy of Sciences
سال: 2010
ISSN: 1736-6046
DOI: 10.3176/proc.2010.3.05